Core Role and Working Principle of Titanium Cathode Plates in Copper Recovery from Etching Solution

Jun 15, 2026

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Core Role and Working Principle of Titanium Cathode Plates in Copper Recovery from Etching Solution

Titanium cathode plates are core components in the electrolytic copper recovery process from spent etching solutions, which are widely generated in industries such as printed circuit boards (PCBs) and metal processing. The core function of these plates is to act as the cathode in the electrolytic system, enabling the reduction and deposition of copper ions from the etching solution onto the plate surface through electrochemical reactions, thereby achieving the dual goals of copper resource recycling and etching solution regeneration.

The working principle is based on the electrolysis reaction: when direct current is applied to the electrolytic cell, copper ions (Cu²⁺) in the spent etching solution migrate toward the titanium cathode plate under the action of an external electric field. Upon reaching the cathode surface, the copper ions gain electrons and undergo a reduction reaction, depositing as high-purity metallic copper on the surface of the titanium cathode plate. Meanwhile, the etching solution after copper removal can be regenerated and reused, reducing environmental pollution and production costs.

Compared with other cathode materials such as stainless steel and pure copper, titanium cathode plates have unique advantages in this process. They can maintain stable performance in the highly corrosive environment of etching solutions (which often contain acidic, alkaline or chloride-rich components), avoid corrosion failure, and ensure the continuity and stability of the copper recovery process. Additionally, the stable oxide film formed on the surface of titanium facilitates the subsequent stripping of deposited copper, improving production efficiency and the quality of recovered copper.

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